Here's my two truly rare items - an original script, and cast & crew Glory Book, from Star Wars.
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The script is a hybrid between the 4th Draft (green pages) and the Revised 4th Draft (pink pages). The pink pages, which are the later version, go up to the scene where the Falcon leaves Tatooine. I'm guessing therefore that the script was produced for the Tunisia shoot, which was the first part of the movie to be filmed. The earlier 4th Draft has some notable differences from the filmed version, such as Ben surviving the Death Star and appearing in the rest of the movie.
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The Glory Books are black and white photo albums that were produced in limited numbers as thank you gifts to key cast and crew members for their contributions to Star Wars. This copy is a photographers proof (there are reference numbers and notes on the reverse of some of the pages), and is lacking a dedication, but has the signatures of George Lucas and Gary Kurtz on the final page.
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These two items are definitely amongst the centre pieces of my collection.