I'm a painter and decorator. Do not put pva on plaster, ever. New plaster takes about a week to dry, but several months to fully cure. Wait a week or two at least, a dehumidifyer will speed up the process. When ready to go, apply a lightly watered (5% extra water, a small cupful or less will suffice) first coat, it's supposed to drink in to mesh with the substate, applying pva doesn't allow paint to bond with the plaster and will only cause the paint to form a skin and can be prone to failure / lifting.
When dry, apply any fillers or caulking needed (levelling with a wet filling knife), then when ready for next coat, put on thinly (called a 'mist' coat). When dry, lightly abrade any imperfections then put on a finishing coat.
Top tips - buy good quality rollers and brushes e.g. Purdy brushes are the pros choice and with care will last years.
Don't buy cheap paint, it's inferior in coverage and durability, use either Dulux or Johnstones vinyl matt. Or use vinyl silk for bathrooms.
A few quality sundries can last for many years and are a great investment such as cotton twill dustsheets, quality scraper and filling knives, button release extension pole, paint kettle + skuttle (not trays).
If you need to seal poor surfaces, try Zinsser 123, sticks like hell to most things. Try your local trade paint store, they will be happy for your business, will give good advice and many will give a discout to local residents, or set up a cash accout for free. The money saved will mean your good quality materials will cost about the same as poor stuff from BnQ.
Hope some of this is of use, feel free to ask away if I can be of further assistance.
